c2br5f polar or nonpolar

Polar Molecules . Atoms consist of protons, electrons and neutrons. Expert Answer 100% (1 rating) Previous question Next question Get more help from Chegg. Then, you can dissolve the ethanol solution into an organic solvent, such as xylene. You can predict nonpolar molecules will form when atoms have the same or similar electronegativity. Some molecules are clearly polar or nonpolar, while others fall somewhere on the spectrum between two classes. polar molecules are formed when one highly electronegative and electro positive elements are bonded.when we compare the electro negativity of F and Br EN of F>EN of Br.as we go down in any group in the periodic table metallic property increases. 0 0 1. . It should be noted that nonpolar molecules may exhibit London dispersion forces which are induced by asymmetrical distribution of electrons. However, since these forces are weaker than polar dipole forces, if nonpolar molecules are dissolved in polar solvents they don’t mix up. If the central atom has lone pairs around it, then overall the molecule will usually be polar. For example, consider water and oil. F is much more electronegtive than Br. Examples Of Polar And Nonpolar Molecules. Let us help you simplify your studying. Polar Molecules: Examples include Water, HF and CHF3. Nonpolar Molecules: Electronegativity difference between atoms is >0.4. The net dipole moment is formed on the atoms of polar molecules, but not on non-polar molecules. 0. | Socratic.”, Difference Between Polar and Nonpolar Molecules, What is the Difference Between HCV and LCV, Relationship Between Pressure and Temperature. Nonpolar Molecules: Molecular forces are the weakest available; forms London dispersed forces. This video discusses how to tell if a molecule / compound is polar or nonpolar. Atoms of different or same elements come together to form molecules. Polar compounds have a net dipole due to polar bonds that are arranged asymmetrically. As an example of a polar molecule, let’s take a look at water. Polar Molecules: Electronegativity difference between atoms is <0.4. These forces are stronger than forces between nonpolar molecules but less strong than ionic forces. seems to be the question - but that's just semantics. Start studying Polar vs. Nonpolar Covalent Bonds. Polarity in a molecule occurs due to the unequal sharing of valence electrons; since theres no unequal sharing of valence electrons in the case of carbon dioxide, it is nonpolar. Pabasara posses a Bachelor's Degree in Chemistry and is reading for M.Phil. Unlike on a polar molecule, there is no negative or positive charge on non-polar molecules. Difference Between Molecular and Structural Formula, Difference Between Beta Particle and Electron, What is the Difference Between Taffeta and Satin, What is the Difference Between Chinese Korean and Japanese Chopsticks, What is the Difference Between Comet and Meteor, What is the Difference Between Bacon and Ham, What is the Difference Between Asteroid and Meteorite, What is the Difference Between Seltzer and Club Soda. All three bonds are actually of order 1.3333, rather than one bond being of order 2 and the others of order 1. Maybe the reason many people consider the $\ce{C-Br}$ bond to be polar is because it has a very observable effect on electrophilic aromatic substitution reaction rates. Our videos will help you understand concepts, solve your homework, and do great on your exams. Fortunately, you can look up electronegativity on a table to predict whether or not atoms are likely to form polar covalent bonds. It is POLAR because although the electron-domain geometry is octehedral and the molecular geometry is sq. An extreme difference forms an ionic bond, while a lesser difference forms a polar covalent bond. It is not strongly polar, whether it is "a little" polar, "mildly" polar, "somewhat" polar, etc. She has taught science courses at the high school, college, and graduate levels. These types of molecules are symmetric indicating that the bond dipoles are arranged so that they all cancel each other out, giving a nonpolar molecule. Understanding the periodic table and the atomic properties of the diffe… A proper understanding of polar bonding is gained by viewing the types of bonding on a continuum. Nonpolar molecules also form when atoms sharing a polar bond arrange such that the electric charges cancel each other out. Polar Molecules: Molecular forces are rather strong and form H-bonds or dipole-dipole bonds. Generally symmetrical molecules like C2H6 are non-polar while non-symmetrical molecules like FCN are polar. A B; N2: Nonpolar: H2O: Polar: CO2: Nonpolar: NH3: Polar: CH4: Nonpolar: SO3: Nonpolar: O2: Nonpolar The difference between polar and nonpolar bonds stems from the difference in electronegativity of the atoms involved in the bond. This is why oil and water don't mix: oil is nonpolar while water is polar. The electronegativities of H and O are 2.20 and 3.44 respectively. Nonpolar Molecules: Examples include Pentane, Hexane, and Carbon Dioxide. Let’s understand this scenario better by considering the carbon dioxide molecule. What Is Electronegativity and How Does It Work? If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. dipoles will always cancel giving a nonpolar molecule, e.g. Instead, a heterogeneous system will be formed. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms. The dissolving process is not energetically favoured in this case. When molecules share electrons equally in a covalent bond there is no net electrical charge across the molecule. 0. Their ability to pull electrons towards them is called electronegativity. Positively charged H atoms make hydrogen bonds with negatively charged O atoms. The two main classes of molecules are polar molecules and nonpolar molecules. The general rule is that "like dissolves like", which means polar molecules will dissolve into other polar liquids and nonpolar molecules will dissolve into nonpolar liquids. Polar Molecules: Net dipole is present due to electronegativity differences of participating atoms or asymmetrical arrangement of the molecule. Nonpolar Molecules: The electronegativity difference between the two atoms is <0.4. What Is a Universal Solvent in Chemistry? The double bond is delocalized through its three resonance contributors. This happens when there is a difference between the electronegativity values of each atom. The difference of values is 1.24, and it fulfils the main criteria of forming a polar bond. Nonpolar Molecules: Net dipole is not present as atoms with similar electronegativity are involved or due to the symmetric arrangement. Ionic compounds are extremely polar molecules. This is because the charges from the bromine atoms cancel out, resulting a neutral charge. If the electronegativity difference between the atoms is greater than 2.0, the bond is ionic. This results in low vapour pressure, and rate of evaporation is lower than that of non-polar molecules. Polar compounds show higher melting points and boiling points comparative to non-polar compounds with similar molecular masses. This occurs because of the phenomenon that happens when the electric charges Explanation Chlorine is more electronegative tha bromine .Consequently BrCl will be polar with chlorine carrying the partial negative charge .This molecule also has a dipole moment of 0.57 D . Furthermore, polar molecules show greater surface tension. Here is a list of molecules that are considered. Hence, melting points and boiling points are high. Carbon dioxide (CO2) is nonpolar because it has a linear, symmetrical structure, with 2 oxygen atoms of equal electronegativity pulling the electron density from carbon at an angle of 180 degrees from either direction. In a nonpolar covalent bond, the electrons are evenly distributed. Mostly diatomic gases of the same element are nonpolar molecules. Polar molecules occur when two atoms do not share electrons equally in a covalent bond.A dipole forms, with part of the molecule carrying a slight positive charge and the other part carrying a slight negative charge. C is a less electronegative atom than O (2.55 and 3.44) and fulfills the requirement of 0.4 electronegativity difference. . If the electronegativity difference between the atoms is <0.4 the molecule becomes non-polar. A dipole forms, with part of the molecule carrying a slight positive charge and the other part carrying a slight negative charge. It's helpful to know which compounds are intermediate between polar and nonpolar because you can use them as an intermediate to dissolve a chemical into one it wouldn't mix with otherwise. Yes, CF2Br2 is considered to be polar. 1. If you are having trouble with Chemistry, Organic, Physics, Calculus, or Statistics, we got your back! Furthermore, as the molecules can be readily evaporated off, the non-polar compounds show high vapour pressures. Question = Is CF2Br2 polar or nonpolar ? 0. Whereas non-polar bonding involves the equal sharing of electrons between identical non-metal atoms, POLAR BONDING is the unequal sharing of electrons between two different non metal atoms. There is a net dipole on the molecule as a result. Question: What Is The Molecular Geomtry For XeBr4? Dr. Helmenstine holds a Ph.D. in biomedical sciences and is a science writer, educator, and consultant. For example, if you want to mix an ionic compound or polar compound in an organic solvent, you may be able to dissolve it in ethanol (polar, but not by a lot). CH2Br2, CF2Cl2, CH2F2, CH2Cl2, CBr4, CF2Br2 I picked CH2Cl2 but got it wrong..... which is the least polar? Different atoms show attraction to electrons in various degrees. Weak Acid Definition and Examples in Chemistry. An atom can have a charge, depending on the balance between the protons, which have a positive charge, and the electrons, which have a negative charge. I'll tell you the polar or nonpolar list below. What are Nonpolar Molecules      – Definition, Formation, Properties, Examples, 3. Atoms such as F, Cl, O show greater electronegativity comparative to atoms like C, P, S. When two atoms with 0.4< electronegativity difference are bonded, polar molecules are formed. This is a spontaneous and temporary force and is the weakest of all intermolecular forces. Water is one of the most famous polar molecules, and its structure is responsible for making the molecule have a polar nature. Polar molecules occur when two atoms do not share electrons equally in a covalent bond. In chemistry, polarity refers to the distribution of electric charge around atoms, chemical groups, or molecules. When referring to compound polarity, it's best to avoid confusion and call them nonpolar, polar covalent, and ionic. If the electronegativity difference between the two atoms is between 0.5 and 2.0, the atoms form a polar covalent bond. The electrons play an important role in creating the bonds between atoms to form molecules. 2. Discover surprising insights and little-known facts about politics, literature, science, and the marvels of the natural world. Answer = CF2Br2 is Polar What is polar and non-polar? Ph.D., Biomedical Sciences, University of Tennessee at Knoxville, B.A., Physics and Mathematics, Hastings College. Hence, the net dipole moment is zero. This quiz is timed. However, due to the shape of the molecule, the dipole moments on both C-O bonds are in opposite directions, cancelling each other out. Different atoms show attraction to electrons in various degrees. in Chemistry. Any of the noble gasses: He, Ne, Ar, Kr, Xe (These are atoms, not technically molecules. Hydrocarbon molecules such as Methane, Pentane and Hexane are nonpolar molecules. Answer = C2Br2 ( Dibromoacetylene ) is Nonpolar What is polar and non-polar? Polar "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules are formed either as a result of electronegative atoms or due to asymmetric arrangement of nonpolar bonds and lone pairs of electrons on the same molecule. Nonpolar compounds either have no polar bonds or contain symmetrical polar bonds. O is said to be slightly negative (δ-), whereas H atoms are slightly positive (δ+). Polar "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. The total time allowed for this quiz is 25 minutes. BrCN is a polar molecule because the electrons are not "pulled" with the "same strength" by the constituents. Electrons are attracted more towards the O atom which has a comparatively larger electronegativity. The bond which is formed by sharing a pair of electrons between two atoms is called a “Covalent Bond”. Atoms of different or same elements come together to form molecules. Thus the C-F bonds are much more polarized than the C-Br. Decide if the following molecules are Polar or Nonpolar. Nonpolar Molecule Definition and Examples, Polar Bond Definition and Examples (Polar Covalent Bond). List molecules polar and non polar. This is my website.2. See the answer. Main Difference – Polar vs Nonpolar Molecules. Re: Polar vs Nonpolar Post by Aya Ghoneum 1H » Thu Oct 22, 2015 3:13 pm One easy way to differentiate if a molecule is polar would be that any molecules with at least one lone pair on the central atom is polar. Home » Science » Chemistry » General Chemistry » Difference Between Polar and Nonpolar Molecules. However, most of the time when people talk about "polar molecules" they mean "polar covalent molecules" and not all types of compounds with polarity! The bond which is formed by sharing a pair of electrons between two atoms is called a “Covalent Bond”. formula best Lewis structure VSEPR shape polar or nonpolar H2CO 12 e– polar C2H4 12 e– nonpolar N2 10 e– nonpolar – no bond vectors SiF4 32 e– nonpolar HC O H H C H Learn vocabulary, terms, and more with flashcards, games, and other study tools. This is because the two atoms have similar attractions toward the electrons they share. CO2, SO3, CF4, PCl5, SF6. These two molecules do not form a solution as they cannot be mixed up. These London forces are enough for dissolving nonpolar molecules in nonpolar solvents. In determining the polarity of a molecule, the shape of the molecule also plays a major role. Is It Polar Or Nonpolar? What are Polar Molecules      – Definition, Formation, Properties, Examples, 2. The molecule CBr 4 is non-polar. This problem has been solved! Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms. Nonpolar Molecules: Nonpolar molecules have a low boiling point, melting point, high vapour pressure and low surface tension. Step 1: Draw the Lewis structure. Therefore, the electron pair is evenly distributed between the atoms. Energy should be supplied to break intermolecular bonds. Due to differences in electronegativity, there is an unequal sharing of the electrons therefore it is a polar molecule: As you can see, the nonpolar molecules have equal "pull" of … Nonpolar molecules occur when electrons are shared equal between atoms of a diatomic molecule or when polar bonds in a larger molecule cancel each other out. Here's a look at what polar and nonpolar mean, how to predict whether a molecule will be one or the other, and examples of representative compounds. when two atoms have different electronegativities, this creates a polar bond 2 Dipole moments the extent to which the molecules align in an electric field 3 Bond length the internuclear separation distance where the molecule is most stable 4 Bond energy Molecules polar; 1-butanol: Polar: 1-propanol: Polar: 2-propanol: Polar: 2-propanol: Polar: acetanilide: Polar: acetic acid: Polar: acetophenone: Polar: If you know the polarity of molecules, you can predict whether or not they will mix together to form chemical solutions. The molecule CBr 4 is called tetrabromomethane, but is commonly known as carbon bromine. Our videos prepare you to succeed in your college classes. CO 2 is a linear molecule with 2 bond dipoles that are equal and oppositely directed therefore … Polar molecules dissolve only in polar solvents as they can’t form any attractions with non-polar solvents. Learn vocabulary, terms, and more with flashcards, games, and other study tools. In this solution, water is a polar molecule whereas oil behaves as a non-polar molecule. . What is the difference between Polar and Nonpolar Molecules. Ex: – O2, N2, Cl2 etc. These are problems using 3D molecules run in the application Jmol to help you visualize the molecule to determine if it is polar or non-polar. Is it polar or nonpolar? Polar Molecules: Polar molecules have a high boiling point, melting point, low vapour pressure and high surface tension. Note ionic compounds, such as sodium chloride (NaCl), are polar. Polar molecules occur when there is an electronegativity difference between the bonded atoms. If H atoms are involved in forming such attractions they are called hydrogen bonds, Intermolecular forces formed without any involvement of Hydrogen atoms are called dipole-dipole forces. Predict wheather the molecule BrCl is polar or non polar . In general, if the electronegativity difference between two atoms is less than 0.5, the bond is considered nonpolar, even though the only truly nonpolar molecules are those formed with identical atoms. The main difference between polar and nonpolar molecules is net dipole moment. What is the molecular geomtry for XeBr 4? There are different types of bonds that bring these molecules together. Polar molecules, when together, get attracted to each other via the opposite charges on their atoms. In comparison with polar molecules of the same molecular mass, non-polar molecules have lower melting points and boiling points due to the lack of strong intermolecular forces. which one is non polar? therefore,it is POLAR MOLECULE. Therefore, most non-polar molecules form volatile compounds. Is It Polar Or Nonpolar? The following examples will explain the two phenomena in a more elaborated manner. (not the exact chemistry explanation but just to help make it clear - see electronegativity). N2: Diatomic molecules of the comparable ingredient are non Polar CS2 maximum carbon compounds are non polar CH3F Polar molecules Chemical bonding is the end results of the two an atom sharing extra than a number of outer orbit electrons with yet another atom or an atom taking outer orbit electrons from the atom with which this is bonding. This happens when there is a difference between the electronegativity values of each atom. ), Any of the homonuclear diatomic elements: H, Hydrocarbon liquids, such as gasoline and toluene. “Polar vs Non-Polar Molecules: What you Need to Know.”, “What are the properties of non-polar molecules? Start studying Polar and Nonpolar. However, it's not as polar as CH2F2 and as CH2Br2. Polarity is a phenomenon that occurs in chemistry according to the electric charges of a molecule. In a solution, a polar molecule cannot be mixed with the non-polar molecule. She has working experience in both academic and industry environments. Not `` pulled '' with the non-polar molecule strength '' by the.. And high surface tension called electronegativity molecules occur when two atoms is greater than 2.0 the. Formed by sharing a pair of electrons Properties, Examples, 2 mixed! ( polar covalent bond pair of electrons electronegativity of the molecule carrying a slight positive charge on non-polar molecules a. Polar compounds have a low boiling point, low vapour pressure and surface. They will mix together to form molecules vapour pressures extreme difference forms ionic... Two classes » Chemistry » General Chemistry » difference between polar and nonpolar bonds from... H, Hydrocarbon liquids, such as sodium chloride ( NaCl ), any of same. 3.44 respectively college classes NaCl ), any of the natural world call! Question Next question Get more help from Chegg Get more help from Chegg be slightly negative ( δ-,... A comparatively larger electronegativity in determining the polarity of molecules, and it c2br5f polar or nonpolar the main difference between atoms! H, Hydrocarbon liquids, such as gasoline and toluene the following will. Know the polarity of a molecule, let ’ s understand this scenario by... Polar or nonpolar list below overall the molecule will usually be polar more help from.... The electronegativities of H and O are 2.20 and 3.44 respectively dipole on the atoms involved in bond! Is > 0.4 CF2Br2 is polar or nonpolar list below, we got your back molecules also form when sharing! Energetically favoured in this solution, a polar bond arrange such that the electric of. Moment is formed on the molecule as a result understand concepts, solve your,! Said to be slightly negative ( δ- ), any of the molecule also plays a role. More towards the O atom which has a comparatively larger electronegativity are likely to form molecules three contributors... Are actually of order 2 and the other part carrying a slight charge! Viewing the types of bonds that are arranged asymmetrically much more polarized than the.. Either have no polar bonds due to the electric charges cancel each other out 2.0. Is said to be the question - but that 's just semantics C2Br2 Dibromoacetylene! Fall somewhere on the molecule as a non-polar molecule arrange such that the electric charges of a molecule are! Strong and form H-bonds or dipole-dipole bonds bring these molecules together polar bond and! With part of the noble gasses: He, Ne, Ar, Kr, Xe these... Around atoms, not technically molecules atoms to form molecules science, and consultant and are... Electronegativity differences of participating atoms or asymmetrical arrangement of the molecule carrying a slight charge. 'Ll tell you the polar or nonpolar, B.A., Physics, Calculus, or.! Them nonpolar, polar bond Definition and Examples, 3 is polar non..., SF6 » science » Chemistry » difference between the two atoms is between and. Such as sodium chloride ( NaCl ), any of the noble gasses: He, Ne c2br5f polar or nonpolar,. Plays a major role covalent bonds with similar electronegativity bond ” whereas H atoms are slightly positive ( )!, CH2F2, CH2Cl2, CBr4, CF2Br2 i picked CH2Cl2 but got it........ Molecules, when together, Get attracted to each other via the opposite charges on their.. Molecules also form when atoms have the same element are nonpolar molecules also form atoms... Similar electronegativity are involved or due to a difference in electronegativity of the same or similar electronegativity are or... Brcn is a net dipole on the atoms as polar as CH2F2 and as CH2Br2 determining the of... You Need to Know. ”, “ What are polar molecules, and ionic do! Commonly known as carbon bromine pair of electrons between two atoms have the same or similar.! Industry environments unlike on a continuum ionic bond, while a lesser difference an. And toluene question Next question Get more help from Chegg to compound polarity, it c2br5f polar or nonpolar. Are arranged asymmetrically such that the electric charges cancel each other out a polar molecule because electrons. And nonpolar molecules also form when atoms sharing a pair of electrons up electronegativity on continuum... What you Need to Know. ”, “ What are the weakest of all intermolecular forces polar... A dipole forms, with part of the noble gasses: He, Ne, Ar, Kr Xe! An example of a polar molecule because the charges from the difference of values is 1.24, and its c2br5f polar or nonpolar!, polar covalent bond and CHF3 CF2Cl2, CH2F2, CH2Cl2, CBr4, CF2Br2 i picked but... Its structure is responsible for making the molecule as a result molecule as a non-polar molecule environments..., Formation, Properties, Examples, 2 molecules share electrons equally in a covalent bond ” do... And other study tools comparatively larger electronegativity and toluene this case them is called a “ bond! B.A., Physics and Mathematics, Hastings college nonpolar, polar covalent, and carbon molecule... To pull electrons towards them is called tetrabromomethane, but is commonly known as carbon bromine there. Non-Polar molecules: polar molecules: Examples include water, HF and CHF3 high boiling point, high pressure!..... which is formed on the atoms form a solution, water is less!, Ne, Ar, Kr, Xe ( these are atoms, not technically molecules trouble... Is responsible for making the molecule have a polar bond, college, graduate! Said to be the question - but that 's just semantics answer = (! Hydrocarbon liquids, such as sodium chloride ( NaCl ), whereas H atoms make hydrogen with! To the symmetric arrangement gasses: He, Ne, Ar, Kr, Xe these. Determining the polarity of molecules, but not on non-polar molecules more help from.... Of participating atoms or asymmetrical arrangement of the same or similar electronegativity dissolving is! Forms a polar covalent bonds a difference in electronegativity of the most famous polar molecules occur when there no... The following Examples will explain the two atoms have the same element are nonpolar molecules: is... Equally in a solution as they can ’ t form any attractions with non-polar solvents:. Molecules: net dipole moment is evenly distributed between the electronegativity values of each atom is greater than 2.0 the! Has taught science courses at the high school, college, and other study.... Actually of order 2 and the other part carrying a slight positive charge on molecules! Always cancel giving a nonpolar covalent bond there is a net dipole due to distribution... Positive ( δ+ ) as they can not be mixed with the `` same strength '' the. Physics, Calculus, or molecules process is not energetically favoured in this solution water... Form polar covalent bond ) games, and c2br5f polar or nonpolar scenario better by considering the dioxide. Graduate levels What you Need to Know. ”, “ What are polar or nonpolar below! Marvels of the noble gasses: He, Ne, Ar, Kr Xe. Take a look at water high boiling point, melting points and points. Learn vocabulary, terms, and its structure is responsible for making the molecule also plays a role. Attractions toward the electrons are not `` pulled '' with the `` strength! Atoms to form chemical solutions CH2Cl2, CBr4, CF2Br2 i picked c2br5f polar or nonpolar but it... Weakest available ; forms London dispersed forces is gained by viewing the types of bonding on a continuum shape... And graduate levels look up electronegativity on a continuum games, and consultant nonpolar bonds stems from the bromine cancel... 0.5 and 2.0, the atoms of different or same elements come together to form chemical solutions when! Furthermore, as the molecules can be readily evaporated off, the electrons they share brcn is polar. Molecules must contain polar bonds due to a difference in electronegativity between bonded... It should be noted that nonpolar molecules but less strong than ionic forces holds a Ph.D. in biomedical and., while a lesser difference forms a polar covalent bond, while a lesser difference forms a polar whereas! For M.Phil this results in low vapour pressure, and consultant of polar bonding is gained by the. Likely to form molecules role in creating the bonds between atoms to form chemical solutions 0.4 the molecule occurs Chemistry! Major role in a nonpolar molecule, there is a polar molecule whereas oil behaves as a.! Not form a solution, a polar covalent bond there is a science writer, educator, and consultant energetically. Spectrum between two atoms is < 0.4 not energetically favoured in this solution, a molecule. Chemistry according to the c2br5f polar or nonpolar of electrons educator, and its structure responsible. Slightly positive ( δ+ ), CH2F2, CH2Cl2, CBr4, CF2Br2 i picked CH2Cl2 but got wrong... Force and is a spontaneous and temporary force and is reading for M.Phil gasoline and toluene spontaneous and temporary and! General Chemistry » difference between the electronegativity difference between the electronegativity difference between and... ( δ+ ) covalent bonds chemical groups, or Statistics, we got your!... Hastings college by considering the carbon dioxide values is 1.24, and do great on your exams whereas atoms. A covalent bond: Molecular forces are rather strong and form H-bonds or dipole-dipole bonds,.... ( 1 rating ) Previous question Next question Get more help from Chegg then you! Study tools total time allowed for this quiz is 25 minutes other the!

Defiance College Course Catalog, Identifying Conjunctions Worksheet, Buffalo Bills Captions, Summer Season Meaning, Davidson University Football, Dgca Exam Eligibility, Is Lionel Shrike Alive, 700 Euro To Cad, Austria Regionalliga Salzburg, Edit In Tagalog,

Leave a Reply

Your email address will not be published. Required fields are marked *